Volume 3,Issue 5
导电聚合物基柔性超级电容器电极材料的研究进展与展望
随着化石燃料能源的日益枯竭，电化学储能技术，尤其是超级电容器，因其高功率密度和超长循环寿命而备受关注。导电聚合物，特别是具有供体-受体（D-A）结构的共轭聚合物，这种聚合物也具有显著的优势，比如良好的电化学性能、导电性能，也正是因为其具有这些优势，其未来也有着较好的发展前景。本文系统综述了柔性超级电容器研究进展，重点讨论导电聚合物基柔性电极的构建策略、性能优势及其在柔性储能器件中的应用进展，并展望了未来研究方向。
[1] 刘华艳, 陈逸飞, 杨梦召, 等. 二维材料基超级电容器的容量与倍率性能提升策略[J]. 物理化学学报, 2025, 41 (6): 100063.
[2] Pameté E, Köps L, Kreth F A, et al. The Many Deaths of Supercapacitors: Degradation, Aging, and Performance Fading[J]. Advanced Energy Materials, 2023: 2301008.
[3] Sun Y, Zhao X, Zhu G, et al. Twisted ladder-like donor-acceptor polymers as electrode materials for flexible electrochromic supercapacitors[J]. Electrochimica Acta, 2020, 333: 135495.
[4] Liu Y Y, Li X C, Wang S, et al. Self-templated synthesis of uniform hollow spheres based on highly conjugated three-dimensional covalent organic frameworks[J]. Nature Communications, 2020, 11 (1): 5561.
[5] Scott S, Mukherjee P, Lei C, et al. The effect of using alternative binders and second life graphite materials on the electrochemical performance of lithium-ion battery electrodes[J]. Journal of Power Sources, 2024, 594: 233993.
[6] 孙学文, 张克良, 李晨, 等. 超级电容器概述: 机理、材料、器件和安全特性[J]. 电工电能新技术, 2025, 44 (10): 117-135.
[7] Wang Y, Wu X, Han Y, et al. Flexible supercapacitor: overview and outlooks[J]. Journal of Energy Storage, 2021, 42: 103053.
[8] Tao R, Wang T, Fan J, et al. Ionothermal synthesis of carbon/TiO2 nanocomposite for supercapacitors [J]. ChemNanoMat 2022, 8: e202200075.
[9] 黄继伟, 钱学仁, 安显慧, 等. 柔性基金属氧化物超级电容器电极材料的研究进展[J]. 功能材料, 2019, 50 (8): 08040-08050.
[10] Peng C, Zhang S, Jewell D, et al. Carbon nanotube and conducting polymer composites for supercapacitors[J]. Progress in Natural science, 2008, 18(7): 777-788.
[11] Quintero D, Matsuya H, Iwai M, et al. Controlling Dielectric Film Defects to Increase the Breakdown Voltage of Conductive Polymer Solid Capacitors[J]. ACS Applied Materials & Interfaces, 2024.